Product ID:TRISODIUM PHOSPHATE, CRYSTALLINE, CPE897001
MSDS Date:10/31/1990
FSC:6810
NIIN:00N056652
MSDS Number: CDNBH

OLIN CORP

120 LONG RIDGE RD
STAMFORD, CT 06904
US

Emergency Phone: 800-654-6911

Info Phone: 203-356-3449

Cage: 8X135

OLIN CORP CHEMICALS GROUP

STAMFORD, CT 06904 US

Telephone: 203-356-3449,CHEMTREC 800-242-9300

Cage: 53084

PHOSPHORIC ACID, TRISODIUM SALT, DODECAHYDRATE; (TRISODIUM

CAS: 10101-89-0

RTECS: TC9575000

Fraction By Weight: 95-100%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

SODIUM HYDROXIDE (CERCLA)

CAS: 1310-73-2

RTECS: WB4900000

Fraction By Weight: 1-5%

OSHA PEL 2 MG/M3

ACGIH TLV: 2 MG/M3, C

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

SITUATIONS FROM RPTD OVEREXP, IMPAIRMENT OF LUNG

RTECS: 9999999ZZ

RPTD EXPOS MAY CAUSE SEV IRRIT, DRYNESS/FLAKING &

RTECS: 9999999ZZ

BE EXPECTED THAT RPTD INGEST WOULD CAUSE TISS DMG TO

RTECS: 9999999ZZ

BASED ON IRRIT & CORR PROPERTIES IT WOULD BE

RTECS: 9999999ZZ

IF NAUS, HDCH/DIZZ IS EXPERD,

RTECS: 9999999ZZ

SYMPS DISAPPEAR. IF BRTHG IS DFCLT, ADMIN OXYG, KEEP

RTECS: 9999999ZZ

INHALES ENOUGH VAP TO LOSE CONSCIOUSNESS, PERS SHOULD

RTECS: 9999999ZZ

IMMED. IF BRTHG HAS STOPPED, ARTF RESP SHOULD BE

RTECS: 9999999ZZ

NIOSH APPROVED RESPIRATORY PROTECTION BEFORE THE

RTECS: 9999999ZZ

DUST MAY BE SUPPRESSED BY USE OF WATER

RTECS: 9999999ZZ

IS HVR THAN & 20% SOL @ 20C(68F) IN WATER. NOTIFY

RTECS: 9999999ZZ

FLOW AROUND SPILL IF POSS & SAFE TO DO SO. IF UNABLE

RTECS: 9999999ZZ

FILTRATION DAM TO REMOVE MATL. REMOVE W/VACUUM

RTECS: 9999999ZZ

CREATE

RTECS: 9999999ZZ

BACK IN ORIGINAL CNTNR. CONTAINERIZE & LBL ALL SPILL

RTECS: 9999999ZZ

USING STRONG DETERGENT & FLUSH W/LG AMTS OF WATER.

RTECS: 9999999ZZ

ADDNL NIOSH APPRVD RESP PROT IS NEC WHEN SPILL/FIRE

RTECS: 9999999ZZ

APPRVD SCBA POS PRESS UNIT. ADDNL PROT CLTHG MUST BE

RTECS: 9999999ZZ

ARE NOT LTD TO BOOTS, GLOVES, HARD HAT, ANSI APPRVD

RTECS: 9999999ZZ

IMPERVIOUS CLTHG, I.E., CHEMICALLY IMPERMEABLE SUIT.

RTECS: 9999999ZZ

POLYVINYL CHLORIDE, BUTYL RUBBER & VITON. PROD

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT) 4.5 G/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:IRRIT TO NOSE, MOUTH,
THROAT & LUNGS. MAY ALSO CAUSE BURNS TO RESP TRACT WHICH CAN RSLT
IN COUGH, WHEEZING, CHOKING, SHORTNESS OF BREATH, CHEST PAIN &
IMPAIRMENT OF LUNG FUNC. HIGH CONCS C AN RSLT IN PERM LUNG DMG.
SKIN:MAY CAUSE MOD TO SEV IRRIT & BURNS TO AREA CONTACTED. SYMPS
MAY INCL (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:REDNESS, SWELL (EDEMA), SCAB FORM &
DESTRUCT OF TISS. EYE:DIRECT CONT CAUSES SEV IRRIT & BURNS POTNTLY
RSLTG IN PERM DMG & IMPAIRMENT OF VISION. INGEST:MAY RSLT IN SEV
IRRIT &/OR BURNS OF MOU TH, THROAT & STOM & GASTROENTERITIS (NAUS,
VOMIT, LETHARGY, DIARR, ABDOM PAIN, BLEEDING/ULCERATION). SEV DMG
TO (SUPDAT)
Medical Cond Aggravated by Exposure:RESPIRATORY DISEASE, SUCH AS ASTHMA
OR EMPHYSEMA.

First Aid:EYES:IMMED FLUSH W/LG AMTS OF WATER FOR AT LST 15 MINS, OCCAS
LIFTING UPPER & LOWER LID. CALL MD AT ONCE. SKIN:IMMED FLUSH
W/WATER FOR 15 MINS. WASH CONTAM SKIN W/SOAP & WATER. IF IRRIT
DEVELS, CALL M D. IF CLTHG COMES IN CONT W/PROD, LAUNDER BEFORE
RE-USE. INGEST:IMMED DRINK LG QTYS OF WATER. DO NOT INDUCE VOMIT.
CALL MD AT ONCE. DO NOT GIVE ANYTHING BY MOUTH IF PERS IS UNCON/IF
HAVING (ING 7)

Extinguishing Media:NOT APPLICABLE - CHOOSE EXTINGUISHING MEDIA
SUITABLE FOR SURROUNDING MATERIALS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . USE WATER TO COOL CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:EVACUATE ALL NON-ESSNTL PERS. HAZ CONCS IN AIR
MAY BE FOUND IN LOC SPILL AREA & IMMED DOWNWIND. UTILIZE EMER
RESPONSE PPE PRIOR TO START OF ANY RESPONSE. REMOVE ALL SOURCES OF
IGNIT. STOP SOURCE OF SP ILL AS SOON AS POSS & NOTIFY APPROP PERS.
(ING 12)
Neutralizing Agent:THIS MATL MAY BE NEUT FOR DISP; CONT OCEAN AT
800-OLIN-911 BEFORE BEGINNING.

Handling and Storage Precautions:AVOID CONT W/SKIN, EYES & CLTHG. DO
NOT STORE AT TEMPS >52C(125F). SHELF LIFE:2 YRS. ALUMINUM INCOMPAT
FOR PACKAGING, STORING OR TRANSPORT.
Other Precautions:HAZ CARBON MONOXIDE CAN FORM UPON CONT W/FOOD &
BEVERAGE PRODS IN ENCLSD SPACES & CAN CAUSE DEATH. DO NOT TAKE
INTERNALLY. CORROSIVE TO SKIN, EYES, MUC MEMBS & RESP TRACT.
HARMFUL IF INHALED, SWALLOWE D/EXPOS TO SKIN/EYES.

Respiratory Protection:RESPIRATORY PROTECTION NOT NORMALLY NEEDED. IF
SIGNIFICANT DUSTING OCCURS, WEAR A NIOSH APPROVED DUST/MIST
RESPIRATOR.
Ventilation:USE LOCAL EXHAUST VENTILATION TO MAINTAIN DUST LEVELS TO
BELOW THE TLV.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(SUPDAT)
Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE
SHOWER . NEOPRENE BOOTS, APRONS/IMPERMEABLE SUIT TO AVOID SKIN &
EYE CONT.
Work Hygienic Practices:UPON CONTACT W/SKIN OR EYES, WASH OFF W/WATER.
Supplemental Safety and Health
PH @ 25C:12(1% SOLN). WASTE DISP METH:W/ALL RELEVANT LOC, STATE & FED
LAWS & REGS REGARDING TREATMENT, STOR & DISP FOR HAZ & NONHAZ
WASTES. EYE PROT:& FULL LGTH FCSHLD . EFTS OF OVEREXP:GI TRACT
W/POTNTL TO CAUSE PERFORATION. CHRONIC:INHAL:MAY CAUSE SIMILAR
SYMPS AS DESCRIBED UNDER ACUTE INHAL. IN EXTREME (ING 3)

Melt/Freeze Pt:M.P/F.P Text:165F,74C
Decomp Temp:Decomp Text:165F,74C
Spec Gravity:1.62
pH:SUPDAT
Solubility in Water:20% @ 20C
Appearance and Odor:WHITE, CRYSTALLINE SOLID; NO ODOR.
Percent Volatiles by Volume:NONE

Stability Indicator/Materials to Avoid:NO
ALUMINUM.
Stability Condition to Avoid:TEMPS >74C(165F) - LOOSES WATER OF
CRYSTALLIZATION. EXPOS TO HIGH HUMIDITY; PRODUCT IS HYGROSCOPIC.
Hazardous Decomposition Products:NONE KNOWN.

Waste Disposal Methods:AS NONHAZ SOLID WASTE IT SHOULD BE DISP OF I/A/W
LOC, STATE & FED REGS BY DISP IN SECURE CHEM LANDFILL. CARE MUST BE
TAKEN TO PVNT ENVIRON CONTAM FROM USE OF MATL. USER HAS
RESPONSIBILITY TO DISP OF U NUSED MATL, RESIDUES, CNTNRS IN
COMPLIANCE(SUPDAT)

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